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欧盟限制纺织品中使用33种有害化学物质

嘉峪检测网        2018-10-15 17:18

在过去十年中,欧盟大大减少了公民对有害化学品的接触,欧盟委员会不断评估如何进一步加强对消费者、工人和环境的保护。在此背景下,欧盟委员会通过修订REACH法规,对服装,鞋类和其他纺织品使用的已知致癌和生殖毒性的33种物质(CMR物质)采取了新的限制措施。这些化学品可能在经常接触人体皮肤时特别有害。

 

根据欧洲化学品管理局的科学和技术建议以及广泛征求意见的结果,新要求规定了在服装和纺织品中使用CMR物质的最大浓度限制,并禁止超过这些限制的产品进入欧盟市场。它们将在欧盟官方公报发布后24个月内生效。委员会还发布了关于限制的解释性指南,该指南将在官方期刊上公布后提供。

 

附件

33种物质(CMR物质)

Substances

Index- No

CAS No

EC No

Concentration limit by weight

Cadmium and its compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)镉及其化合物

 

-

-

-

1 mg/kg after extraction (expressed as Cd metal that can be extracted from the material)

Chromium VI compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)六价铬化合物

-

-

-

1 mg/kg after extraction (expressed as Cr VI that can be extracted from the material)

Arsenic compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)砷化合物

-

-

-

1 mg/kg after extraction (expressed as As metal that can be extracted from the material)

Lead and its compounds (listed in Annex XVII, Entry 28, 29, 30, Appendices 1-6)铅及其化合物

-

-

-

1 mg/kg after extraction (expressed as Pb metal that can be extracted from the material)

Benzene苯

601-020-00-8

71-43-2

200-753-7

5 mg/kg

Benz[a]anthracene苯并蒽

601-033-00-9

56-55-3

200-280-6

1 mg/kg

Benz[e]acephenanthrylene

601-034-00-4

205-99-2

205-911-9

1 mg/kg

benzo[a]pyrene; benzo[def]chrysene

601-032-00-3

50-32-8

200-028-5

1 mg/kg

Benzo[e]pyrene

601-049-00-6

192-97-2

205-892-7

1 mg/kg

Benzo[j]fluoranthene

601-035-00-X

205-82-3

205-910-3

1 mg/kg

Benzo[k]fluoranthene

601-036-00-5

207-08-9

205-916-6

1 mg/kg

Chrysene

601-048-00-0

218-01-9

205-923-4

1 mg/kg

Dibenz[a,h]anthracene二苯并蒽

601-041-00-2

53-70-3

200-181-8

1 mg/kg

α, α,α,4-tetrachlorotoluene; p-chlorobenzotrichloride

对氯三氯甲苯 

602-093-00-9

5216-25-1

226-009-1

1 mg/kg

α, α,α-trichlorotoluene; benzotrichloride三氯甲苯

602-038-00-9

98-07-7

202-634-5

1 mg/kg

α-chlorotoluene; benzyl chloride氯化苄

602-037-00-3

100-44-7

202-853-6

1 mg/kg

Formaldehyde甲醛

605-001-00-5

50-00-0

200-001-8

75 mg/kg 

1,2-benzenedicarboxylic acid; di-C 6-8-branched alkylesters, C 7-rich苯二羧酸

607-483-00-2

71888-89-6

276-158-1

1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B

Bis(2-methoxyethyl) phthalate邻苯二甲酸二酯

607-228-00-5

117-82-8

204-212-6

1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity  or reproductive toxicity, category 1A or 1B

Diisopentylphthalate

607-426-00-1

605-50-5

210-088-4

1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity or reproductive toxicity, category 1A or 1B

Di-n-pentyl phthalate (DPP)邻苯二甲酸二戊烷基

607-426-00-1

131-18-0

205-017-9

1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity  or reproductive toxicity, category 1A or 1B

Di-n-hexyl phthalate (DnHP)邻苯二甲酸二己基

607-702-00-1

84-75-3

201-559-5

1000 mg/kg (individually or in combination with other phthalates in this entry or in other entries of Annex XVII that are classified in Part 3 of Annex VI to Regulation (EC) No 1272/2008 in any of the hazard classes carcinogenicity, germ cell mutagenicity  or  reproductive toxicity, category 1A or 1B

N-methyl-2-pyrrolidone; 1-methyl-2-pyrrolidone (NMP)

606-021-00-7

872-50-4

212-828-1

3000 mg/kg

N,N-dimethylacetamide (DMAC)

616-011-00-4

127-19-5

204-826-4

3000 mg/kg

N,N-dimethylformamide; dimethyl formamide (DMF)

616-001-00-X

68-12-2

200-679-5

3000 mg/kg

1,4,5,8-tetraaminoanthraquinone; C.I. Disperse Blue 1

611-032-00-5

2475-45-8

219-603-7

50 mg/kg

Benzenamine, 4,4'-(4-iminocyclohexa-2,5- dienylidenemethylene)dianiline hydrochloride; C.I. Basic Red 9

611-031-00-X

569-61-9

209-321-2

50 mg/kg

[4-[4,4'-bis(dimethylamino)benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride; C.I. Basic Violet 3 with ≥ 0,1 % of Michler's ketone (EC no. 202-027-5)

612-205-00-8

548-62-9

208-953-6

50 mg/kg

4-chloro-o-toluidinium chloride

612-196-00-0

3165-93-3

221-627-8

30 mg/kg

2-Naphthylammoniumacetate

612-071-00-0

553-00-4

209-030-0

30 mg/kg

4-methoxy-m-phenylene diammonium sulphate; 2,4-diaminoanisole sulphate

612-200-00-0

39156-41-7

254-323-9

30 mg/kg

2,4,5-trimethylaniline hydrochloride

612-197-00-6

21436-97-5

-

30 mg/kg

Quinoline

613-281-00-5

91-22-5

202-051-6

50 mg/kg '

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